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21 tháng 1 2022

\(n_{H_2SO_4}=\frac{114.20\%}{98}\approx0,23mol\)

\(n_{BaCl_2}=\frac{400.5,2\%}{208}=0,1mol\)

PTHH: \(BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)

Xét tỷ lệ: \(n_{BaCl_2}< n_{H_2SO_4}\)

Vậy \(H_2SO_4\) dư

\(\rightarrow n_{H_2SO_4\left(\text{dư}\right)}=0,23-0,1.2=0,03mol\)

Theo phương trình \(n_{BaSO_4}=n_{BaCl_2}=0,1mol\) và \(n_{HCl}=2n_{BaCl_2}=0,2mol\)

\(\rightarrow m_{BaSO_4}=0,1.233=23,3g\) và \(m_{HCl}=0,2.36,5=7,3g\)

\(m_{H_2SO_4\left(\text{dư}\right)}=0,03.98=2,94g\)

\(\rightarrow m_{ddsau}=114+400-23,3=490,7g\)

\(\rightarrow C\%_{H_2SO_4\left(\text{dư}\right)}=\frac{2,94}{490,7}.100\%\approx0,599\%\)

\(C\%_{HCl}=\frac{7,3}{490,7}.100\%\approx1,49\%\)

Vậy chọn A.

7 tháng 11 2019

a) 2AgNO3+CaCl2---->2AgCl+Ca(NO3)2

n AgNO3=1,7/170=0,01(mol)

n CaCl2=2,22/111=0,02(mol)

----> CaCl2 dư

Theo pthh

n AgCl=n AgNO3=0,01(mol)

m AgCl=0,01.143,5=14,35(g)

V dd sau pư=70+30=`100ml=0,1(l)

n CaCl2 dư=0,02-0,005=0,015(mol)

CM CaCl2=0,015/0,1=0,15(M)

Theo pthh

n Ca(NO3)2=1/2 n AgCl=0,005(mol)

CM Ca(NO3)2=0,005/0,1=0,05(M)

Bài 2

BaCl2+H2SO4--->BaSO4+2HCl

a) n BaCl2=400.5,2/100=20,8(g)

n BaCl2=20,8/208=0,1(mol)

m H2SO4=100.1,14.20/100=22,8(g)

n H2SO4=22,8/98=0,232(mol)

---->H2SO4 dư

Theo pthh

n BaSO4=n BaCl2=0,1(mol)

m BaSO4=0,1.233=23,3(g)

b) m dd sau pư=400+114-23,3

=490,7(g)

Theo pthh

n HCl=2n BaCl2=0,2(mol)

C%HCl=\(\frac{0,2.36,5}{490,7}.100\%=1,88\%\)

n H2SO4 dư=0,232-0,1=0,132(mol)

C% H2SO4=\(\frac{0,132.98}{490,7}.100\%=2,64\%\)

7 tháng 11 2019

B1:

\(n_{AgNO3}=0,01\left(mol\right);n_{CaCl2}=0,2\left(mol\right)\)

PTHH:\(2AgNO3+CaCl2\rightarrow2AgCl2\downarrow+Ca\left(NO3\right)2\)

Trước :0,01................0,02..........................................................(mol)

Pứng:\(0,01\rightarrow0,005\rightarrow0,01\rightarrow0,005\)

Dư: 0............................0,015......................................................(mol)

\(m\downarrow_{AgCL}=0,01.143,5=1,435\left(g\right)\)

Trong dd sau phản ứng chứa: \(\left\{{}\begin{matrix}Ca\left(NO3\right)2:0,005\left(mol\right)\\CaCl2:0,015\left(mol\right)\end{matrix}\right.\)

\(C_{M_{Ca\left(NO3\right)2}}=\frac{0,005}{0,1}=0,05M\)

\(C_{M_{CaCl2}}=\frac{0,015}{0,1}=0,15M\)

Bài 2:\(n_{BaCl2}=\frac{400.5,2}{100.208}=0,1\left(mol\right)\)

\(D=\frac{m_{dd}}{v_{dd}};C\%=\frac{m_{ct}}{m_{dd}}.100\Rightarrow m_{H2SO4}=\frac{D.v.d^2.C\%}{100}=22,8g\)

\(\Rightarrow n_{H2SO4}=0,23\left(mol\right)\)

\(BaCl2+HSO4\rightarrow BaSO4\downarrow+2HCl\)

0,1..............0,1............0,1.................0,2.....(mol)

\(a,m_{\downarrow}=0,1.223=23,3\left(g\right)\)

\(b,m_{dd_{saupu}}=m_{BaCl2}+m_{dd_{H2SO4}}-m_{\downarrow}_{BaSO4}\)

\(=400+1,14.100-23,3=490,7\)

\(\Rightarrow C\%_{HCl}=\frac{0,2.36,5}{490,7}.100\%=1,48\%\)

\(\%H2SO4_{du}=\frac{\left(0,23-0,1\right).98}{490,7}.100=2,59\%\)

30 tháng 4 2018

nNa = \(\dfrac{6,9}{23}\) =0,3 mol

2Na + 2H2O ->2 NaOH + H2

0,3mol ->0,3mol->0,15mol

=>mNaOH = 0,3 . 40 = 12g

=> mdd = 6,9 + 50 - 0,15.2 = 56,6 g

=> C% = \(\dfrac{12}{56,6}\).100% = 21,2%

Giúp mk vớikhocroikhocroi

13 tháng 12 2020

mddH2SO4 = 100 . 1,137 = 113,7

nH2SO4 = 113,7 . 20%/98 = 0,232 mol

nBaCl2 = 400 . 5,29%/208 = 0,1 mol

                 H2SO4 + BaCl2 —> BaSO4 + 2HCI

Bđ:            0,232      0,1

Pứ:            0,1        0, 1         0,1       0,2

Sau pứ:      0,132         0

mBaSO4 = 0,1.233 = 23,3 gam

Khối lượng dung dịch sau khi lọc bỏ kết tủa:

mddB = mddH2SO4 + mddBaCl2 - mBaSO4 = 490,4

C%HCI = 0,2.36,5/490,4 = 1,49%

C%H2SO4 dư = 0,132.98/490,4 = 2,64%

\(n_{BaCl_2}=\dfrac{208.15\%}{208}=0,15\left(mol\right)\\ n_{H_2SO_4}=\dfrac{150.19,6\%}{98}=0,3\left(mol\right)\\ BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ Vì:\dfrac{0,15}{1}< \dfrac{0,3}{1}\Rightarrow H_2SO_4dư\\ n_{H_2SO_4\left(p.ứ\right)}=n_{BaSO_4}=n_{BaCl_2}=0,15\left(mol\right)\\ n_{HCl}=2.0,15=0,3\left(mol\right)\\ n_{H_2SO_4\left(dư\right)}=0,13-0,15=0,15\left(mol\right)\\ m_{HCl}=0,3.36,5=10,95\left(g\right)\\ m_{BaSO_4}=233.0,15=34,95\left(g\right)\\ m_{H_2SO_4\left(dư\right)}=0,15.98=14,7\left(g\right)\\ m_{ddsau}=208+150-34,95=323,05\left(g\right)\\ C\%_{ddHCl}=\dfrac{10,95}{323,05}.100\approx3,39\%\)

\(C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{14,7}{323,05}.100\approx4,55\%\)

14 tháng 12 2023

\(a)n_{H_2SO_4}=\dfrac{58,8.20}{100.98}=0,12mol\\ n_{BaCl_2}=\dfrac{200.5,2}{100.208}=0,05mol\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\\ \Rightarrow\dfrac{0,12}{1}>\dfrac{0,05}{2}\Rightarrow H_2SO_4.dư\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)

0,05         0,05             0,05           0,1

\(m_{BaSO_4}=0,05.233=11,65g\\ b)m_{dd}=58,8+200-11,65=247,15g\\ C_{\%HCl}=\dfrac{0,1.36,5}{247,15}\cdot100=1,48\%\\ C_{\%H_2SO_4,dư}=\dfrac{\left(0,12-0,05\right).98}{247,15}\cdot100=2,78\%\)

5 tháng 8 2020

a) mBaCl2 = 20,8 g => nBaCl2 = 0,1 mol

mH2SO4 = \(\frac{m_{dd}C\%}{100}\) = \(\frac{100.1,14.20}{100}\) = 22,8 g => nH2SO4 ≃ 0,2 mol

BaCl2 + H2SO4➝ BaSO4↓ + 2HCl

bđ: 0,1 0,2

pứ: 0,1 0,1

dư: 0 0,1

Vậy BaCl2 hết, H2SO4 dư, bài toán tính theo BaCl2

nBaSO4 = nBaCl2 = 0,1 mol

=> mBaSO4 = 23,3 g

b) nHCl = 2nBaCl2 = 0,1 mol

=> CM = 1 M

nH2SO4 = 0,1 mol => CM = 1 M

16 tháng 8 2023

a, \(H_2SO_4+BaCl_2\rightarrow BaSO_{4\downarrow}+2HCl\)

b, Ta có: \(m_{H_2SO_4}=114.20\%=22,8\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{22,8}{96}=0,2375\left(mol\right)\)

\(m_{BaCl_2}=400.5,2\%=20,8\left(g\right)\Rightarrow n_{BaCl_2}=\dfrac{20,8}{208}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,2375}{1}>\dfrac{0,1}{1}\), ta được H2SO4 dư.

Theo PT: \(n_{BaSO_4}=n_{BaCl_2}=0,1\left(mol\right)\Rightarrow m_{BaSO_4}=0,1.233=23,3\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=n_{BaCl_2}=0,1\left(mol\right)\\n_{HCl}=2n_{BaCl_2}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,2375-0,1=0,1375\left(mol\right)\)

Ta có: m dd sau pư = 114 + 400 - 23,3 = 490,7 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,1375.98}{490,7}.100\%\approx2,75\%\\C\%_{HCl}=\dfrac{0,2.36,5}{490,7}.100\%\approx1,49\%\end{matrix}\right.\)

29 tháng 12 2019

1)

nBaCl2=\(\frac{\text{150.10%.1,04}}{208}\)=0,075 mol

nH2SO4= \(\frac{\text{50.20%.1,225}}{98}\)=0,125 mol

PTHH:

BaCl2+ H2SO4→ BaSO4+ 2HCl

0,075___0,075____0,075___0,15

mdd sau pư= 150.1,04+50.1,225- 0,075.233= 199,75 g

C%HCl=\(\frac{\text{0,15.36,5}}{199,75.100\%}\)=2,74%

C% H2SO4 dư= \(\frac{\text{(0,125- 0,075).98}}{199,75}\)=2,45%

2)

nBa=\(\frac{\text{10,275}}{137}\)=0,075 mol

nH2So4 dư= 0,125- 0,075= 0,05 mol

PTHH:

Ba + H2SO4 → BaSO4+ H2

0,025__0,025___ 0,025

Ba + 2HCl → BaCl2+ H2

0,0375_0,075__0,0375

Ba + 2H2O→ Ba(OH)2 + H2

0,0125 0,0125

mdd sau pư= \(\frac{\text{199,75}}{2}\)+ 10,275- 0,025.233- 0,025.2=104,275g

C%Bacl2= \(\frac{\text{0,0375.208}}{104,275.100\%}\)=7,48%

C% Ba(OH)2= \(\frac{\text{0,0125.171}}{104,275.100\%}\)=2,05%